The Physics and Chemistry of Contact
In winemaking, maceration refers to the process of steeping grape must with the solid parts of the berry—skins, seeds, and sometimes stems. The pulp of almost all wine grape varieties (with rare exceptions like Alicante Bouschet) is colorless. If you press the juice and immediately separate it from the skins, you get white wine. To obtain red wine, the must must spend time in contact with the pomace.
During this contact, two parallel processes occur: the extraction of coloring pigments (anthocyanins) and the extraction of polyphenols (tannins). Anthocyanins are responsible for the depth and hue of the color, from pale ruby to almost black. Tannins shape the wine's structure, its astringency, and its ageing potential. Maceration also infuses the must with varietal aromas, which are primarily concentrated in the outer layers of the skins.