The Physics of Aroma Evaporation
Each grape variety possesses a unique set of aromatic compounds. Phenols and esters evaporate at different rates depending on the wine's surface area in contact with air. A wide bowl accelerates oxidation and releases heavy molecules, while a narrow one retains delicate aromas.
The size and shape of the glass determine which part of the bouquet reaches your nose first. Furthermore, the rim diameter and the angle of the walls force us to tilt our head differently when sipping. This directs the flow of wine to specific zones of the tongue, altering the initial impression of acidity or sweetness.