Micro-oxygenation and Tannins
During ageing, wine interacts with oxygen. The pores of oak wood allow microscopic amounts of air to pass through. This process is called micro-oxygenation. It stabilizes the color of red wine and softens harsh tannins, making the texture rounder and silkier.
In addition to oxygen, the wood imparts its own tannins and aromatic compounds to the wine. Vanillin is responsible for the recognizable sweetish note, while wood lactones bring hints of coconut. The intensity of this exchange depends on the vessel's volume: a classic 225-liter barrica imparts flavor faster than larger casks.